|
|Section2= |Section3= |Section7= |Section8= }} Vanadium hexacarbonyl is the inorganic compound with the formula V(CO)6. It is a blue-black volatile solid. This highly reactive species is noteworthy from theoretical perspectives as a rare isolable homoleptic metal carbonyl that is paramagnetic. Most species with the formula Mx(CO)y follow the 18e rule, whereas V(CO)6 has 17 valence electrons.〔C. Elschenbroich, A. Salzer ”Organometallics : A Concise Introduction” (2nd Ed) (1992) from Wiley-VCH: Weinheim. ISBN 3-527-28165-7〕 == Synthesis == Traditionally V(CO)6 is prepared in two-steps via the intermediacy of () :4 Na + VCl3 + 6 CO + 2 diglyme → ()() + 3 NaCl The resulting anion is oxidized with acid:〔Liu, X.; Ellis, J. E. "Hexacarbonylvanadate(1 :2 ()− + H3PO4 → 2 V(CO)6 + H2 + 2 H2PO4− 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「vanadium hexacarbonyl」の詳細全文を読む スポンサード リンク
|